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'Aggregation induced emission' active iridium(III) complexes with applications in mitochondrial staining

Identificadores del recurso

2046-2069

http://hdl.handle.net/2445/106627

667374

Procedència

(Dipòsit Digital de la Universitat de Barcelona)

Fitxa

Títol:: 'Aggregation induced emission' active iridium(III) complexes with applications in mitochondrial staining
Tema:: Mitocondris; Citotoxicitat per mediació cel·lular; Síntesi orgànica; Mitochondria; Cell-mediated cytotoxicity; Organic synthesis
Descripció:: Two new bis-cyclometalated iridium(III) complexes, [Ir(F2ppy)2(L)] and [Ir(ppy)2(L)], where F2ppy 1⁄4 2-(20,40- difluoro)phenylpyridine, ppy 1⁄4 2-phenylpyridine and L 1⁄4 1,2-((pyridin-2-ylimino)methyl)phenol, have been designed and synthesized by a convenient route. We have univocally characterized their structure by 1H NMR, 19F NMR, HRMS and SXRD. Both complexes exhibit strong 'Aggregation Induced Emission (AIE)' activity, which has been investigated using spectroscopy measurements, ab initio quantum chemical calculations and by analysing their crystal packing. One of the complexes has been shown to have a potential application as a non-toxic bio-imaging probe for mitochondrial staining.
Font:: Articles publicats en revistes (Ciència dels Materials i Química Física)
Idioma:: English
Relació:: Reproducció del document publicat a: https://doi.org/10.1039/c6ra24792j; RSC Advances, 2017, vol. 7, p. 5642-5648; https://doi.org/10.1039/c6ra24792j
Autor/Productor:: Alam, Parvej; Dash, Subhra; Climent Biescas, Claudia; Kaur, Gurpreet; Choudhury, Angshuman Roy; Casanova i Casas, David; Alemany i Cahner, Pere; Chowdhury, Rajdeep; Laskar, Inamur Rahaman
Editor:: Royal Society of Chemistry
Drets:: cc-by (c) Alam, Parvej et al., 2017; http://creativecommons.org/licenses/by/3.0/es; info:eu-repo/semantics/openAccess
Data:: 2017-02-07T14:55:22Z; 2017-01-17
Tipo de recurso:: info:eu-repo/semantics/article; info:eu-repo/semantics/publishedVersion
Format:: 7 p.; application/pdf

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1. <dc:title>'Aggregation induced emission' active iridium(III) complexes with applications in mitochondrial staining</dc:title>
2. <dc:creator>Alam, Parvej</dc:creator>
3. <dc:creator>Dash, Subhra</dc:creator>
4. <dc:creator>Climent Biescas, Claudia</dc:creator>
5. <dc:creator>Kaur, Gurpreet</dc:creator>
6. <dc:creator>Choudhury, Angshuman Roy</dc:creator>
7. <dc:creator>Casanova i Casas, David</dc:creator>
8. <dc:creator>Alemany i Cahner, Pere</dc:creator>
9. <dc:creator>Chowdhury, Rajdeep</dc:creator>
10. <dc:creator>Laskar, Inamur Rahaman</dc:creator>
11. <dc:subject>Mitocondris</dc:subject>
12. <dc:subject>Citotoxicitat per mediació cel·lular</dc:subject>
13. <dc:subject>Síntesi orgànica</dc:subject>
14. <dc:subject>Mitochondria</dc:subject>
15. <dc:subject>Cell-mediated cytotoxicity</dc:subject>
16. <dc:subject>Organic synthesis</dc:subject>
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