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β-Functionalization of 4a-aza-8a-boranaphthalene via Iridium-catalyzed C-H Borylation

Identificadores del recurso

Advanced Synthesis and Catalysis, 2023, v. 365, n. 15, p. 2545-2552

1615-4150

http://hdl.handle.net/10017/59187

10.1002/adsc.202300408

AR/0000044491

Advanced Synthesis and Catalysis

365

2552

15

2545

Procedencia

(e_Buah - Biblioteca Digital de la Universidad de Alcalá)

Ficha

Título:: β-Functionalization of 4a-aza-8a-boranaphthalene via Iridium-catalyzed C-H Borylation
Tema:: BN-naphthalene; C-H activation; iridiumcross-coupling; catalysis; Química; Chemistry
Descrición:: A general method for the functionalization of 4a-aza-8a-boranaphthalene in the position ? to the nitrogen atom has been developed. This method is based on a regioselective iridium-catalyzed C?H activation process for the introduction of a boronate group, which can subsequently be transformed into a variety of aryl or alkynyl groups via cross-coupling reactions. Selective mono- or difunctionalization can be achieved by controlling the reaction conditions during the borylation step. The photophysical properties of the obtained 3- or 3,6-substituted BN-naphthalenes have been evaluated, and some of them have been found to be significantly fluorescent, with fluorescence quantum yields up to 0.85.; Ministerio de Ciencia e Innovación; Instituto de Salud Carlos III
Idioma:: English
Relación:: info:eu-repo/grantAgreement/MICINN//PID2020-115128RB-I00/ES/; info:eu-repo/grantAgreement/MICINN//PID2021-1242470B-C21/ES/; info:eu-repo/grantAgreement/MICINN//PID2020-118384GB-I00/ES/; info:eu-repo/grantAgreement/ISCIII//ISCIIIRICORS2040%2FRD21%2F0005%2F0005/ES/
Autor/Productor:: Valencia Nieto, Isabel; Sucunza Sáenz, David; Mendicuti Madrid, Francisco Enrique Javier; García García, Patricia; Vaquero López, Juan José
Otros colaboradores/productores:: Universidad de Alcalá. Departamento de Química Analítica, Química Física e Ingeniería Química; Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica; Unidad docente Química Orgánica
Dereitos:: © The Authors; Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0); http://creativecommons.org/licenses/by-nc-nd/4.0/; info:eu-repo/semantics/openAccess
Data:: 2024-01-09T10:07:46Z; 2023-07-02; 2024-01-09T10:07:16Z
Tipo de recurso:: info:eu-repo/semantics/article; info:eu-repo/semantics/publishedVersion
Formato:: application/pdf

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