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2D copper-imidazolate framework without thermal treatment as an efficient ORR electrocatalyst for Zn–air batteries

Identificadores del recurso

http://hdl.handle.net/10396/24307

Jatorria

(Helvia: Repositorio Institucional de la Universidad de Córdoba)

Fitxa

Izenburu:: 2D copper-imidazolate framework without thermal treatment as an efficient ORR electrocatalyst for Zn–air batteries
Tema:: Oxygen reduction reaction; Electrocatalysts; Electrocatalysis; Zn-air batteries; Metal–organic framework
Deskribapen:: To face unmet energy demands, the search for more stable, low-cost, and scalable electrocatalyst materials is imperative. Within this context, single-atom catalysts (SACs) have drawn considerable attention due to their maximum atom utilization. With this idea in mind, we have synthesized a new ultrathin and water-stable 2D Cu-based metal-organic framework (2DCIFs), which presents a notable electrocatalytic activity for oxygen reduction reaction (ORR) in alkaline media without the need of calcination, which makes the difference when compared to most MOF-based electrocatalysts. The designed MOF-based SAC consists of single-atom sites (isolated and accessible Cu) coordinated to imidazole carboxylic ligands, giving rise to Cu-N4O actives sites confined into a 2D-nanostructured network. This unique structure, along with the ultrathin nature of nanosheets that favors mass transport and electrical conductivity, and the high chemical stability of these 2DCIFs are the key features of the excellent ORR performance, which occurs by a direct four-electron transfer pathway, an onset potential of 0.86 V vs RHE and a maximum current density of 6.4 mA·cm-2. These good catalytic properties of 2DCIFs have allowed their use as efficient air electrodes in alkaline flooded and all-solid-state Zn-air batteries. In the former case, 2DCIFsbased air electrodes presented a specific power density of 91.2 kW·cm-2·kg-1 and a specific capacity of 296.2 A·h·g-1, significantly exceeding the specific capacity values reported previously for other Cu-based catalysts. Besides, the specific capacity increased to 389.1 A·h·g-1 when 2DCIFs were tested in an all-solid-state Zn-air battery.
Iturri:: Journal of Materials Chemistry A 10, 24590-24597 (2022)
Idioma:: English
Harreman:: https://doi.org/10.1039/D2TA05988F; Gobierno de España. 2019-027527-I; Gobierno de España. PID2019-107665RJ-I00; Gobierno de España. CTQ2016- 78289-P; Gobierno de España. PID2020-112744GB-I00; Gobierno de España. PID2020-113809RB-C33; Gobierno de España. PID2019-104272RB-C55; Gobierno de España. AEI/10.13039/501100011033
Autor/Productor:: Franco, Ana; Salatti Dorado, José Ángel; García-Caballero, Valentín; Lorca, Sebastián; Camacho, Luis; Cano, Manuel; Fernández Romero, A.J.; Delgado, Juan J.; Giner-Casares, Juan J.; Carrillo-Carrión, C.
Argitaratzaile:: Royal Society of Chemistry
Eskubideak:: https://creativecommons.org/licenses/by-nc/4.0/; info:eu-repo/semantics/openAccess
Data:: 2022-11-09T12:51:54Z; 2022
Tipo de recurso:: info:eu-repo/semantics/article
Formatu:: application/pdf

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2. <dc:creator>Franco, Ana</dc:creator>
3. <dc:creator>Salatti Dorado, José Ángel</dc:creator>
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12. <dc:subject>Oxygen reduction reaction</dc:subject>
13. <dc:subject>Electrocatalysts</dc:subject>
14. <dc:subject>Electrocatalysis</dc:subject>
15. <dc:subject>Zn-air batteries</dc:subject>
16. <dc:subject>Metal–organic framework</dc:subject>
17. <dc:description>To face unmet energy demands, the search for more stable, low-cost, and scalable electrocatalyst materials is imperative. Within this context, single-atom catalysts (SACs) have drawn considerable attention due to their maximum atom utilization. With this idea in mind, we have synthesized a new ultrathin and water-stable 2D Cu-based metal-organic framework (2DCIFs), which presents a notable electrocatalytic activity for oxygen reduction reaction (ORR) in alkaline media without the need of calcination, which makes the difference when compared to most MOF-based electrocatalysts. The designed MOF-based SAC consists of single-atom sites (isolated and accessible Cu) coordinated to imidazole carboxylic ligands, giving rise to Cu-N4O actives sites confined into a 2D-nanostructured network. This unique structure, along with the ultrathin nature of nanosheets that favors mass transport and electrical conductivity, and the high chemical stability of these 2DCIFs are the key features of the excellent ORR performance, which occurs by a direct four-electron transfer pathway, an onset potential of 0.86 V vs RHE and a maximum current density of 6.4 mA·cm-2. These good catalytic properties of 2DCIFs have allowed their use as efficient air electrodes in alkaline flooded and all-solid-state Zn-air batteries. In the former case, 2DCIFsbased air electrodes presented a specific power density of 91.2 kW·cm-2·kg-1 and a specific capacity of 296.2 A·h·g-1, significantly exceeding the specific capacity values reported previously for other Cu-based catalysts. Besides, the specific capacity increased to 389.1 A·h·g-1 when 2DCIFs were tested in an all-solid-state Zn-air battery.</dc:description>
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