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A Comprehensive Review of HCN-Derived Polymers

Identificadores del recurso

Processes 9(4): 597(2021)

https://www.mdpi.com/2227-9717/9/4/597

http://hdl.handle.net/20.500.12666/481

10.3390/pr9040597

2227-9717

http://dx.doi.org/10.13039/501100011033

Jatorria

(DIGITAL.INTA)

Fitxa

Izenburu:: A Comprehensive Review of HCN-Derived Polymers
Tema:: HCN-derived Polymers; cyanide chemistry; prebiotic chemistry; multifunctional materials; 2D Materials
Deskribapen:: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited; HCN-derived polymers are a heterogeneous group of complex substances synthesized from pure HCN; from its salts; from its oligomers, specifically its trimer and tetramer, amino-nalono-nitrile (AMN) and diamino-maleo-nitrile (DAMN), respectively; or from its hydrolysis products, such as formamide, under a wide range of experimental conditions. The characteristics and properties of HCN-derived polymers depend directly on the synthetic conditions used for their production and, by extension, their potential applications. These puzzling systems have been known mainly in the fields of prebiotic chemistry and in studies on the origins of life and astrobiology since the first prebiotic production of adenine by Oró in the early years of the 1960s. However, the first reference regarding their possible role in prebiotic chemistry was mentioned in the 19th century by Pflüger. Currently, HCN-derived polymers are considered keys in the formation of the first and primeval protometabolic and informational systems, and they may be among the most readily formed organic macromolecules in the solar system. In addition, HCN-derived polymers have attracted a growing interest in materials science due to their potential biomedical applications as coatings and adhesives; they have also been proposed as valuable models for multifunctional materials with emergent properties such as semi-conductivity, ferroelectricity, catalysis and photocatalysis, and heterogeneous organo-synthesis. However, the real structures and the formation pathways of these fascinating substances have not yet been fully elucidated; several models based on either computational approaches or spectroscopic and analytical techniques have endeavored to shed light on their complete nature. In this review, a comprehensive perspective of HCN-derived polymers is presented, taking into account all the aspects indicated above.; This research was funded by the projects PID2019-104205GB-C21 and PID2019-107442RBC32 from the Spanish Ministerio de Ciencia, Innovacion y Universidades and by the Spanish State Research Agency (AEI) project MDM-2017-0737 Centro de Astrobiologia (CSIC-INTA), Unidad de Excelencia Maria de Maeztu.; Peerreview
Idioma:: English
Harreman:: info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104205GB-C21; info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107442RB-C32/ES/OPERACION CIENTIFICA Y EXPLOTACION DE DATOS EN RLS (RAMAN LASER SPECTROMETER) DE EXOMARS Y SUPERCAM DE MARS2020/
Autor/Productor:: Ruiz Bermejo, M.; De la Fuente, J. L.; Pérez Fernández, C.; Mateo Martí, E.
Argitaratzaile:: Multidisciplinary Digital Publishing Institute (MDPI)
Otros colaboradores/productores:: Unidad Científica de Excelencia María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737; Ruiz Bermejo, M. [0000-0002-8059-1335]; Mateo Martí, E. [0000-0003-4709-4676]; Agencia Estatal de Investigación (AEI)
Eskubideak:: Attribution-NonCommercial-NoDerivatives 4.0 International; MDPI; http://creativecommons.org/licenses/by/4.0/; info:eu-repo/semantics/openAccess
Data:: 2022-02-08T12:10:51Z; 2021-03-29
Tipo de recurso:: info:eu-repo/semantics/article; info:eu-repo/semantics/publishedVersion; http://purl.org/coar/resource_type/c_6501
Formatu:: application/pdf

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2. <mods:name>
  1. <mods:namePart>De la Fuente, J. L.</mods:namePart>
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3. <mods:name>
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4. <mods:name>
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8. <mods:identifier type="citation">Processes 9(4): 597(2021)</mods:identifier>
9. <mods:identifier type="other">https://www.mdpi.com/2227-9717/9/4/597</mods:identifier>
10. <mods:identifier type="uri">http://hdl.handle.net/20.500.12666/481</mods:identifier>
11. <mods:identifier type="doi">10.3390/pr9040597</mods:identifier>
12. <mods:identifier type="e-issn">2227-9717</mods:identifier>
13. <mods:identifier type="funder">http://dx.doi.org/10.13039/501100011033</mods:identifier>
14. <mods:abstract>HCN-derived polymers are a heterogeneous group of complex substances synthesized from pure HCN; from its salts; from its oligomers, specifically its trimer and tetramer, amino-nalono-nitrile (AMN) and diamino-maleo-nitrile (DAMN), respectively; or from its hydrolysis products, such as formamide, under a wide range of experimental conditions. The characteristics and properties of HCN-derived polymers depend directly on the synthetic conditions used for their production and, by extension, their potential applications. These puzzling systems have been known mainly in the fields of prebiotic chemistry and in studies on the origins of life and astrobiology since the first prebiotic production of adenine by Oró in the early years of the 1960s. However, the first reference regarding their possible role in prebiotic chemistry was mentioned in the 19th century by Pflüger. Currently, HCN-derived polymers are considered keys in the formation of the first and primeval protometabolic and informational systems, and they may be among the most readily formed organic macromolecules in the solar system. In addition, HCN-derived polymers have attracted a growing interest in materials science due to their potential biomedical applications as coatings and adhesives; they have also been proposed as valuable models for multifunctional materials with emergent properties such as semi-conductivity, ferroelectricity, catalysis and photocatalysis, and heterogeneous organo-synthesis. However, the real structures and the formation pathways of these fascinating substances have not yet been fully elucidated; several models based on either computational approaches or spectroscopic and analytical techniques have endeavored to shed light on their complete nature. In this review, a comprehensive perspective of HCN-derived polymers is presented, taking into account all the aspects indicated above.</mods:abstract>
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20. <mods:subject>
  1. <mods:topic>HCN-derived Polymers</mods:topic>
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21. <mods:subject>
  1. <mods:topic>cyanide chemistry</mods:topic>
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22. <mods:subject>
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23. <mods:subject>
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  1. <mods:topic>2D Materials</mods:topic>
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